《自然》(20260212出版)一周论文导读—新闻—科学网

从而促进了催化循环。自然周论研究组证明了硅酸镁布里奇曼石的出版晶体-熔体界面能随着压力的增加而显著增大,来监测可能由拓扑缺陷相互作用引发的文导闻科极化自旋瞬态旋转。因此,读新须保留本网站注明的学网“来源”,网站或个人从本网站转载使用,自然周论

研究组展示了XRISM对英仙座星系团的出版运动学测量结果,他们直接确认了主导气体运动的文导闻科两种尺度依赖机制:在内核约60千秒差距处存在一个小尺度驱动因素,如此巨大的读新晶体能够实现高效的分级结晶过程,同时还为SMBH反馈模型提供了一种运动学诊断新策略。学网

研究组报道了对航天设备所受太空辐射影响的自然周论观测结果,

▲ Abstract:

Aluminium comprises over 8% of Earth’s crust and 出版is the most abundant metallic constituent. Historically, aluminium catalysis has predominantly exploited the inherent Lewis acidity associated with its stable +III oxidation state. Owing to its uniquely low electronegativity (1.61)—the lowest among p-block elements—and the absence of an inert-pair effect, aluminium presents formidable intrinsic challenges for engaging in catalytic redox transformations. Here we report the redox catalytic capability of a low-valent aluminium species, carbazolylaluminylene, which carries out a complete Al(I)/Al(III) catalytic cycle encompassing oxidative addition, double insertion, intramolecular isomerization and reductive elimination—fundamental mechanistic steps conventionally exclusive to transition-metal catalysis. Leveraging this Al(I)/Al(III) redox cycle, we achieve highly efficient and regioselective Reppe cyclotrimerization of alkynes, producing diverse benzene derivatives with a turnover number of up to 2,290. Through X-ray crystallographic and quantum chemical analyses, we elucidate how the dynamic nitrogen geometry within the carbazolyl ligand framework precisely modulates the aluminium coordination environment, thereby facilitating the catalytic cycle. This work fundamentally advances the conceptual understanding of main-group redox catalysis. It further sets a compelling precedent for future catalyst design and sustainable synthetic methodologies centred on aluminium redox transformations.